CROWN BATTERY MFG CO -- BATTERIES,WET,FILLED WITH ACID,B 24131-6 -- 6140-01-325-1795
===================== Product Identification ===================== Product ID:BATTERIES,WET,FILLED WITH ACID,B 24131-6 MSDS Date:12/16/1993 FSC:6140 NIIN:01-325-1795 === Responsible Party === Company Name:CROWN BATTERY MFG CO Address:1445 MAJESTIC DR Box:990 City:FREMONT State:OH ZIP:43420-0990 Country:US Info Phone Num:419-334-7181 Emergency Phone Num:419-334-7181/800-777-0782CONSOLIDAT CAGE:1X630 === Contractor Identification === Company Name:CROWN BATTERY MFG CO Address:1445 MAJESTIC DR Box:City:FREMONT State:OH ZIP:43420-0990 Country:US Phone:419-334-7181 CAGE:1X630 Company Name:PETTIBONE TIFFIN CORP SUB OF PETTIBONE CORP Address:235 MIAMI ST Box:City:TIFFIN State:OH ZIP:44883-0099 Country:US CAGE:13841 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III)- TOTAL PERCENT OF INGREDIENTS 1, 2 AND 3 IS 60. CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: SEE ING Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:LEAD OXIDE CAS:1309-60-0 RTECS #:OG0700000 Fraction by Wt: SEE # 1% Other REC Limits:NONE RECOMMENDED Ingred Name:LEAD SULFATE (SARA III) CAS:7446-14-2 RTECS #:OG4375000 Fraction by Wt: SEE # 1% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG(PB)/M3; 9394 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ANTIMONY (SARA III) CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG (SB)/M3; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC (ORGANIC COMPOUNDS) (SARA III) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1018 ACGIH TLV:0.01 MG/M3, A1; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SULFURIC ACID (SARA III) - (25-40% CONCENTRATION) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 8 - 12% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR SULFURIC ACID IS 1 MG/M3. Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, KIDNEY. ACUTE- SULFURIC ACID CAN CAUSE EYE, SKIN, RESPIRATORY & DIGESTIVE TRACTS IRRITATION, BURNS, CORNEAL & LUNG DAMAGE. NO POSSIBILITY OF OVER EXPOSURE OF LEAD UNLESS BATTERY IS DESTROYED. CHRONIC- LEAD MAYCAUSE ANEMIA, KIDNEY & NERVOUS SYSTEM DAMAGE. ACID CAN DAMAGE LUNGS & TEETH. Explanation of Carcinogenicity:CONTAINS ARSENIC WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. ALSO CONTAINS LEAD. Effects of Overexposure:GASTROINTESTINAL UPSET, LOSS OF APPETITE, DIARRHEA, CONSTIPATION, CRAMPING, LACK OF SLEEP, FATIGUE, EYE, SKIN, GASTROINTESTINAL AND RESPIRATORY TRACTS IRRITATION AND BURNS; CORNEAL, TEETH AND LUNG DAM AGE Medical Cond Aggravated by Exposure:INORGANIC LEAD AND ITS COMPOUNDS CAN AGGRAVATE CHRONIC FORMS OF KIDNEY, LIVER AND NEUROLOGIC DISEASES. SULFURIC ACID MISTS CAN AGGRAVATE SKIN DISEASES SUCH AS ECZEMA, DERMATITIS AND LUNG DISEASES. ======================= First Aid Measures ======================= First Aid:OBTAIN MEDICAL ATTENTION IMMEDIATELY IN ALL CASES OF EXPOSURE. EYES/SKIN:FLUSH WITH WATER FOR 15 MINUTES. KEEP EYELIDS OPEN. INHALATION:MOVE TO FRESH AIR. PROVIDE OXYGEN IF NEEDED. INGESTION:DO NOT IN DUCE VOMITING. IF CONSCIOUS, DRINK MILK. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR FIRES IN AREA. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:WATER APPLIED TO SULFURIC ACID GENERATES HEAT AND CAUSES ACID TO SPATTER. REACTS WITH MOST METALS TO YIELD EXPLOSIVE/FLAMMABLE HYDROGEN GAS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. REMOVE COMBUSTIBLES & IGNITION SOURCES (H2 MAY BE PRESENT). CONTAIN BY DIKING & COVER SPILL WITH SODA ASH/QUICKLIME. MIX WELL. CHECK THAT MIXTURE IS NEUTRAL. COLLECT & PLAC E IN A DRUM. DO NOT FLUSH TO SEWER. VENTILATE AREA Neutralizing Agent:SODA ASH (SODIUM CARBONATE), QUICKLIME (CALCIUM OXIDE) ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE NEAR EYEWASH FOUNTAIN AND SAFETY SHOWER. STORAGE AREA SHOULD BE EQUIPPED WITH A DRAIN WHICH CAPTURES SPILLS OF ACID FOR PROPER DISPOSAL. Other Precautions:KEEP TERMINALS COVERED IN PLASTIC CASE. AVOID SHORTING BATTERIES. DO NOT CRACK OR OVERCHARGE BATTERIES. KEEP LIGHTED CIGARETTES, SPARKS, AND FLAMES AWAY FROM CHARGING BATTERIES. KEEP OUT OF REACH OF C HILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE NIOSH-APPROVED ACID-MIST FILTER RESPIRATOR IF 1 MG/M3 TWA IS EXCEEDED (ACID). Ventilation:ADEQUATE GENERAL VENTILATION Protective Gloves:RUBBER Eye Protection:SPLASH-PROOF CHEMICAL GOGGLES Other Protective Equipment:RUBBER APRON AND BOOTS. EYES WASH STATION AND SAFETY SHOWER. USE ACID-PROOF CLOTHING FOR MAJOR SPILLS. Work Hygienic Practices:REMOVE METALLIC JEWELRY-SHOCK POTENTIAL. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING AND DRINKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:C1 NRC/State Lic Num:NOT RELEVANT Spec Gravity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:NOT RELEVENT Appearance and Odor:BATTERY CONTAINING SULFURIC ACID AND LEAD. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTIVE METALS, STRONG BASES, MOST ORGANIC COMPOUNDS, COMBUSTIBLES, STRONG REDUCING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, OVERCHARGING, SMOKING, SPARKS Hazardous Decomposition Products:OXIDES OF LEAD, SULFUR DIOXIDE, SULFUR TRIOXIDE, SULFURIC ACID FUMES, CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS FOR ACID OR LEAD SCRAP. SEND BATTERIES TO LEAD SMELTER FOR RECLAMATION FOLLOWING APPLICABLE FEDERAL, STATE AN D LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.