CROWN BATTERY MFG CO -- BATTERIES,WET,FILLED WITH ACID -- 6140-01-337-0210
===================== Product Identification ===================== Product ID:BATTERIES,WET,FILLED WITH ACID MSDS Date:08/17/1992 FSC:6140 NIIN:01-337-0210 === Responsible Party === Company Name:CROWN BATTERY MFG CO Address:1445 MAJESTIC DR Box:990 City:FREMONT State:OH ZIP:43420-0990 Country:US Info Phone Num:419-334-7181 Emergency Phone Num:800-777-0782,419-334-7181 Preparer's Name:KATHY BUCHANAN CAGE:1X630 === Contractor Identification === Company Name:BATTERY BARN THE Address:124 E WASHINGTON ST Box:City:PETERSBURG State:VA ZIP:23803 Country:US Phone:804-862-3425 CAGE:0ALN9 Company Name:CROWN BATTERY MFG CO Address:1445 MAJESTIC DR Box:City:FREMONT State:OH ZIP:43420-0990 Country:US Phone:419-334-7181 CAGE:1X630 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD/LEAD OXIDE/LEAD SULFATE (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 60% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ANTIMONY (SARA III) CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG SB/M3; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC (SARA III) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 (AS) ACGIH TLV:0.01,A1 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SULFURIC ACID (25%-40% ACID) (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 3-12% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:AVOID CONTACT WITH ELECTROLYTE FROM SPILLED OR BROKEN BATTERY. ELECTROLYTE IS CORROSIVE SULFURIC ACID. ACUTE: ACID MAY CAUSE IRRITATION AND SERIOUS BURNS TO EYES, SKIN, RESPIRATORY SYSTEM, AND DIGEST IVE SYSTEM. CHRONIC: ACID MAY CAUSE SERIOUS BURNS TO EYES, SKIN, RESPIRATORY SYSTEM, AND DIGESTIVE SYSTEM. Explanation of Carcinogenicity:CONTAINS I A [7440-38-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:FROM CONTACT WITH THE ELECTROLYTE: CHEMICAL BURNS OR IRRITATION OF EYES, SKIN, RESPIRATORY SYSTEM, DIGESTIVE SYSTEM. Medical Cond Aggravated by Exposure:EXPOSURE TO ACID MISTS MAY CAUSE LUNG DAMAGE AND AGGRAVATE PULMONARY CONDITION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH AREA WITH LARGE AMOUNTS OF WATER. IF ADVERSE SYMPTOMS DEVELOP, GET MEDICAL ATTENTION. INHALATI ON: MOVE TO FRESH AIR. IF BREATHING DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GIVE MILK TO DRINK. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Extinguishing Media:US MEDIA APPRPREIATE FOR SURROUNDING MATERIALS. DRY CHEMICAL, CARBON DIOXIDE, WATER FOG, WATER. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:WATER APPLIED TO SULFURIC ACID GENERATES HEAT AND CAUSES ACID TO SPATTER. SULFURIC ACID REACTS WITH MOST METALS TO YIELD EXPLOSIVE/FLAMMABLE HYDROGEN GAS. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL USING INERT MATERIALS; VERMICULITE, DRY SAND, EARTH. NEUTRALIZE WITH LIME, SODA ASH, SODIUM BICARBONATE. Neutralizing Agent:SODIUM BICARBONATE, SODA ASH OR LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE SEPARATE FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM FIRE, SPARKS, AND HEAT. PROTECT BATTERY FROM PHYSICAL DAMAGE. DO NOT INCINERATE. Other Precautions:AVOID CONTACT WITH BATTERY ELEMENTS (LEAD OR ACID ELECTROLYTE). CONTACT OF ELECTROLYTE WITH METALS MAY PRODUCE TOXIC SULFUR DIOXIDE FUMES AND MAY ALSO RELEASE FLAMMABLE HYDROGEN GAS. THIS REACTION IS INTENSIFIED WHEN DILUTED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED, FITTED, FULL FACE RESPIRATOR. Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE. VENTILATION SYSTEM MUST BE ACID AND EXPLOSIVE RESISTANT. Protective Gloves:ACID RESISTANT GLOVES. Eye Protection:GOGGLES/FULL FACE PORTECTION. Other Protective Equipment:ACID RESISTANT CLOTHING AND BOOTS. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:203F,95C Melt/Freeze Pt:M.P/F.P Text:-35F TO +10 Vapor Pres:10 @18F Vapor Density:>1 Spec Gravity:1.245-1.295 pH:ACID Solubility in Water:100 Appearance and Odor:ELECTROLYTE: CLEAR LIQUID. SHARP PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUSTIBLES, ORGANIC MATERIALS, STRONG REDUCING AGENTS, METALS, NITRATES, CHLORATES, CARBIDES, FULMINATES, PICRATES. Hazardous Decomposition Products:SULFUR TRIOXIDE, CARBON MONOXIDE, SULFURIC ACID FUMES, SULFUR DIOXIDE. Conditions to Avoid Polymerization:MAY OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.